I believe in the events where you don't register decklists for draft/sealed you are not allowed to sideboard between match postings and the first match of the round. To avoid situations where you scouted the other decks and pre-sideboard for the opponents deck. At least that is how we always played it.
No, you can change your deck at any time you like between matches--you could even sit down in front of your opponent for the next round and change your deck right in front of them, explaining to them point-blank how the changes you're making will improve your matchup. It's major angle-shooting, and if you do it you're probably taking things way too seriously and the people around you are going to think you're a jerk, but it's legal.
I did that once and then felt super bad about it.
Although I believe I lost, and to be fair,
Dormant Sliver is not the best hate card (when you run it out carelessly).