I'm actuallly experimenting with a Planeswalker OC (similar to a Jack Harkness-like character, where it's a part of their lifestyle, and played for laughs in context only when his sex drive is cranked up)
I wanted the character to be Red/White and have a Dack Fayden-style "lovable troublemaker" vibe. I could see a Red/Green character being driven sexually as "my goals include planting my seed wherever it may grow on whatever plane suits me", though I'd like an approachable character who MAY experience one-night-stands, or humorous "not sure how human-on-merfolk would transpire, but I'm up for anything" or to the most extreme, having a disconnected multiplanar harem of sorts, however overall still does it for more overall than just physical gratification, and he does hope that his experiences may lead him to forming a bond with another humanoid with whom he can feel committed to bringing his planeswalking days to an end.